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- W2077100891 abstract "Through in situ reaction of acetylene with a mixture of three triply bonded complexes [ν5-R1C5H4(CO2Mo]2, [ν5-R2C5H4(CO)2W] 2, ν5-R1C5H4(CO)2MoW(CO)2C5H4R2-ν5, prepared by refluxing a diglyme solution of two dimers [ν5-R1C5H4 (CO)3Mo]2 and [ν5-R2C5H4(CO)3W]2, five new μ-alkyne compounds [ν5-MeO2CC5H4(O)2W]2(μ-C2H2) (2a), [ν5-MeO2CC5H4(CO)2MoW(CO)2C5H4Et-ν5] (μ-C2H2) (3a, R1 = H, R2 = CO2Me; 3b, R1 = C(O)Me, R2 = H; 3c, R1 = C(O)Me, R2 = CO2Me; 3d, R1 = CO2Me, R2 = Et) were obtained. Further reaction of 1b with PhCHO in aqueous NaOH solution gave an aldol condensation product, [ν5-PhCHCHC(O)C5H4(CO)2Mo]2 (μ-C2H2) (4), whereas 3b and 3c reacted with NaBH4 in MeOH to afford corresponding reductive products [ν5-MeCH(OH)C5H4(CO)2MoW(CO)2C5H4R-ν5] (5, R = H; 6, R = CO2Me). All these new complexes were fully characterized by combustion analysis, IR, 1H NMR and mass spectroscopy, and by X-ray crystallography." @default.
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- W2077100891 title "Synthesis, reactions and characterization of homo- and heterobimetallic Mo/W μ-alkyne complexes containing functionally substituted cyclopentadienyl ligands: The crystal structure of [ν5-MeO2CC5H4(CO)2MoW(CO)2C5H4Et-ν5](μ-C2H2)" @default.
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- W2077100891 doi "https://doi.org/10.1016/0277-5387(95)00584-6" @default.
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