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- W2077102512 abstract "Spectra of CF4 as pure gas and in mixtures with gaseous He, Ar, Xe and N2 were obtained in the region of the forbidden ν2 band at pressures from about 1 atm up to 100 atm at ambient temperature. The absorption consists of two components depending on the gas pressure. The first, with an integrated intensity (cm−2 Amagat−1) that is independent of pressure, arises through the Coriolis or intramolecular interactions. The second, varying linearly with the partial pressure, is attributable to additional absorption arising during intermolecular binary collisions. The intensity of each of these components was measured and analysed, and from the results we are able to draw some conclusions concerning the collision-induced mechanisms responsible for the absorption." @default.
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- W2077102512 date "2004-08-20" @default.
- W2077102512 modified "2023-10-05" @default.
- W2077102512 title "Intra- and intermolecular components of the ν<sub>2</sub>forbidden band of CF<sub>4</sub>in pure gas and in He, Ar, Xe and N<sub>2</sub>mixtures" @default.
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- W2077102512 doi "https://doi.org/10.1080/00268970412331287151" @default.
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