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- W2077103463 abstract "To evaluate a process at the early stage of its development, one must be able to perform simple calculations to compare all the alternatives. This must be done on a reasonably realistic basis, so that one can make credible decisions; however, the process should not be so detailed and laborious that it becomes too “expensive” to perform for alternatives that can ultimately be discarded. A methodology for performing these calculations has been developed, and this will be illustrated with a case study on Fischer−Tropsch synthesis (FTS). The effect of designing a Fischer−Tropsch (FT) process targeting a particular value of the probability of chain growth (α) on the overall carbon efficiency has been studied using simplified FTS flowsheet models. Two process configurationsnamely, the once-through and recycle processeshave been compared, and it is observed that, for a fixed production rate of liquid fuels at 100% CO conversion, the carbon efficiency for the process with a recycle stream is higher than that of the once-through process for all values of α. However, if the aim is to maximize diesel production by hydrocracking the waxes, it has been determined that an optimal α value should be sought to reduce the cost of hydrocracking very heavy waxes. The incorporation of wax hydrocracking in the two processes reduces the carbon efficiency at all α values beyond ∼0.7, thereby making it uneconomical to produce very-long-chain hydrocarbons." @default.
- W2077103463 created "2016-06-24" @default.
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- W2077103463 date "2006-07-25" @default.
- W2077103463 modified "2023-09-23" @default.
- W2077103463 title "A Process Synthesis Approach To Investigate the Effect of the Probability of Chain Growth on the Efficiency of Fischer−Tropsch Synthesis" @default.
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- W2077103463 doi "https://doi.org/10.1021/ie0505256" @default.
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