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- W2077110250 abstract "The chemical shifts of F/sup 19/ have been observed for a number of metal fluoride complexes in aqueous solution. No simple correlation was found with the electronegativity of the metal ion or the stability of the complex formed. It appears thnt metal cations of high atomic number produce a strong decrease in the magnetic shielding and a rough correlation was obtained with A/d, i.e., ratio of the atomic number of the metal ion to the interatomic distance in the complex. In several cases separate resonances were observed, and assuming that they represent species which exchange fluorines only slowly, lower limits to the lifetime for exchange were calculated. (auth)" @default.
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- W2077110250 date "1959-04-01" @default.
- W2077110250 modified "2023-09-26" @default.
- W2077110250 title "F19 Nuclear Magnetic Resonance of Various Metal–Fluoride Complexes in Aqueous Solution" @default.
- W2077110250 doi "https://doi.org/10.1021/j150574a029" @default.
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