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• W2077121217 abstract "Blends of isotactic polypropylene with amorphous and slightly crystalline ethylene-propylene-diene terpolymer (EPDM), prepared by solution blending, have been investigated by optical microscopy and differential scanning calorimetry. Nucleation and crystallization kinetic parameters, such as nucleation rates, nucleation half times, Avrami-exponents and spherulitic growth rates, have been determined. It has been found that the dispersion of crystalline EPDM in iPP is different from that of amorphous EPDM. Both EPDMs are incorporated into the spherulites, causing a decrease of the maximum growth rate of the iPP spherulites. The surface free energy of the iPP crystals is diminished on adding EPDM to iPP and is accompanied by a higher secondary nucleation rate. From the decrease observed in the Avrami exponent with increasing EPDM concentration in the blend, it has been concluded that nucleation becomes predominantly heterogeneous, as there is a proportional increase in the interfacial area between the two components." @default.
• W2077121217 created "2016-06-24" @default.
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• W2077121217 date "1993-07-01" @default.
• W2077121217 modified "2023-10-16" @default.
• W2077121217 title "The influence of rubber-matrix interfaces on the crystallization kinetics of isotactic polypropylene blended with ethylene-propylene-diene terpolymer (EPDM)" @default.
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• W2077121217 doi "https://doi.org/10.1002/pen.760331403" @default.
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