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- W2077124529 endingPage "4977" @default.
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- W2077124529 abstract "The radii of gyration for a series of poly(ethylene−1-butene) copolymers of varying ethyl branch content were measured as a function of temperature in the melt via small angle neutron scattering (SANS), and their temperature coefficients, d ln C∞/dT = κ, changed from negative to positive. The characteristic ratio C∞ decreased with increasing ethyl branch frequency. When possible, these results were compared with those obtained from ϑ solvents and from rotational isomeric (RIS) state theory. The SANS-based chain dimensions were slightly larger than those obtained from ϑ solvents. The values of κ differed significantly from those extracted from ϑ-solvent measurements. Serious discrepancies with RIS-based calculations were observed." @default.
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- W2077124529 date "1997-08-01" @default.
- W2077124529 modified "2023-10-09" @default.
- W2077124529 title "Melt Chain Dimensions of Poly(ethylene−1-butene) Copolymers via Small Angle Neutron Scattering" @default.
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- W2077124529 doi "https://doi.org/10.1021/ma961408c" @default.
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