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- W2077126665 abstract "A domino addition–reduction sequence to construct three contiguous stereogenic centers with a high level of diastereoselectivity makes use of the chiral camphor-derived thiol 1 in a Michael addition to acyclic α,β-disubstituted α,β-unsaturated ketones 2 (see scheme). The effect of additives was investigated, and it was also shown that compounds 3 are suitable precursors to 1,3-hydroxythiols of type 4. R1=aryl, R2=alkyl, R3=alkyl or phenyl." @default.
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- W2077126665 date "2003-09-25" @default.
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- W2077126665 title "One‐Step Stereocontrol of Three Contiguous Stereogenic Centers in Acyclic Systems: The Tuning Effect of an Additive in a Tandem Asymmetric Michael Addition and Meerwein–Ponndorf–Verley Reduction" @default.
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- W2077126665 doi "https://doi.org/10.1002/anie.200351915" @default.
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