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- W2077130904 abstract "The Raman spectra of LiCl-AlCl3, KCl-AlCl3 and CsCl-AlCl3 melts in the concentration range 50–100 mol.% AlCl3 are presented. The melt structure of these systems are discussed in terms of the species AlCl4−, Al2Cl7−, Al2Cl6 and higher polymers. The relative stabilities of the different species are studied as a function of the cation environment. Perturbation of the AlCl4− and Al2Cl7− vibrations due to the alkali counterion is found and interpreted in terms of change of symmetry, force constants and masses. The bridge structure of Al2Cl7− is discussed." @default.
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- W2077130904 date "1973-04-01" @default.
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- W2077130904 title "Raman spectra of AlCl3-AlkCl and trends in species formation" @default.
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- W2077130904 doi "https://doi.org/10.1016/0022-1902(73)80191-5" @default.
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