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- W2077134389 abstract "The reaction mechanism in the UV photochemistry of 2-chloro-2'-deoxyadenosine (Cladibrine) and 2-bromo-2'-deoxyadenosine in aqueous solution has been studied by laser photolysis at nanosecond time resolution. It is found that excitation at 266 nm wavelength produces heterolytic cleavage of the halogen-carbon bond by one-photon absorption and formation of the unstable 2-hydroxy tautomer of 2'-deoxyisoguanosine as predominant 'primary' product. The 2-hydroxy tautomer then transforms in 10(-6)-10(-5) s into the stable 2-oxo tautomer in an acid-base-catalysed reaction. A reaction mechanism is proposed and discussed in relation to previous UV low-intensity studies of these halogenodeoxyadenosines." @default.
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- W2077134389 date "1999-05-01" @default.
- W2077134389 modified "2023-09-25" @default.
- W2077134389 title "Reaction mechanism in the photochemistry of the antileukaemic agents 2-chloro- and 2-bromo-2′-deoxyadenosine, studied by nanosecond laser flash photolysis" @default.
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- W2077134389 doi "https://doi.org/10.1016/s1011-1344(99)00064-0" @default.
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