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- W2077166273 abstract "Swelling properties and phase diagrams of binary systems composed of polyacrylate networks and a low molecular mass liquid crystal (LMWLC) have been investigated. The networks were prepared by ultraviolet (UV) irradiation of reactive mixtures including a monomer, a crosslinking agent and a photo-initiator. Poly(n-butylacrylate) networks were prepared using two crosslinking agents: 1,6-hexanedioldiacrylate (HDDA) and a mesogenic acrylic acid 6-(4'-(6-acryloyloxy-hexyloxy)biphenyl-4-yl oxy) hexyl ester (AHBH). The obtained dry polyacrylates were characterized by differential scanning calorimetry, and immersed in an excess of a LMWLC solvent 4-cyano-4'-pentylbiphenyl (5CB), forming polymer gels. A detailed study by polarized optical microscopy allowed to determine the swelling degree of the gels and to follow the phase behavior of the solvent inside the polymer matrix in a wide range of temperature. Swelling data were used to establish the phase diagrams in terms of composition and temperature. It was found that the poly(n-butylacrylate) network obtained with the nematic crosslinking agent show fluctuations in the region of the nematic-isotropic transition temperature of 5CB, probably due to the presence of nematic-nematic coupling effects between the nematic solvent and the nematic moieties of AHBH." @default.
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- W2077166273 date "2014-02-01" @default.
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- W2077166273 title "Experimental Study on the Swelling Behavior of Polymer Networks in a Nematic Solvent" @default.
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- W2077166273 doi "https://doi.org/10.1002/masy.201300017" @default.
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