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• W2077169956 abstract "The new method for estimation of Tolman δ-corrections for liquid droplets is proposed on the basis of equation of state. It is revealed that Tait equation of state for such evaluations can be used. The set of estimates was established for δ-correction in the case of H2O and Ar in a wide temperature range. Both cases give δ < 0 that correlates with known estimates. It is proved that |δ| rises with temperature and diverges at critical point. Corresponding critical exponents estimate for Ar(δ ∼ |τ| − a) gives a = 0.5 (here τ=Tc−TTc). Studying of Tolman δ-corrections behavior within the framework of the mean-field theory is resulted in δ=−1σ016pc by using Van der Waals equations of state. Here σ0 is an amplitude factor of the surface tension for the flat surface σ∞ = σ0 τ32. The analysis of experimental data for a set of fluids demonstrates the satisfactory fit of the obtained result with experiment. Using the scaling theory for description of an equation of state of the coexistence curve and surface tension give such δ ∼ τβ−ν, where β and ν are critical exponents. Thus, δ-correction has singular character as critical point approaches." @default.
• W2077169956 created "2016-06-24" @default.
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• W2077169956 date "2003-04-01" @default.
• W2077169956 modified "2023-09-27" @default.
• W2077169956 title "Influence of the drops size on the coefficient of surface tension in a wide range of pressures and temperatures along the coexistence curve" @default.
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• W2077169956 doi "https://doi.org/10.1016/s0167-7322(03)00040-0" @default.
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