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• W2077171053 endingPage "155" @default.
• W2077171053 startingPage "133" @default.
• W2077171053 abstract "The use of concentrated colloidal suspensions is common in several industries such as paints, foodstuffs and pulp and paper. These suspensions are generally composed of strongly interactive particles. If the attractive forces dominate the repulsion and Brownian forces, the particles aggregate to form a three-dimensional network yielding a gel structure. Under flow, the micro-structure of suspensions can be drastically modified and the rheological properties are then governed by structure breakdown and build-up. In this work, we propose a structural network model based on a modified upper convected Jeffreys model with a single relaxation time and a kinetic equation to describe the flow-induced micro-structure evolution. Three distinct kinetic equations are tested for this purpose. The proposed model describes yield and thixotropic phenomena, nonlinear viscoelastic behavior and output signal distortions observed for relatively small strain amplitude during oscillatory measurements, and overshoots observed in stress growth experiments. A comparison of model predictions and experimental data for fumed silica and coating colors is also presented. However, different model parameters must be used to correctly predict the different flow properties indicating that a more versatile or generalized kinetic equation must be proposed." @default.
• W2077171053 created "2016-06-24" @default.
• W2077171053 creator A5003849786 @default.
• W2077171053 creator A5006630382 @default.
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• W2077171053 date "1999-09-01" @default.
• W2077171053 modified "2023-09-29" @default.
• W2077171053 title "Rheological modeling of concentrated colloidal suspensions" @default.
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• W2077171053 doi "https://doi.org/10.1016/s0377-0257(98)00206-7" @default.
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