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• W2077175348 abstract "A convergent synthesis of the nonacyclic BCDEFGHIJ-ring polyether core of gambieric acids, potent antifungal polycyclic ether marine natural products, has been achieved. The present synthesis involved as key features: (i) convergent union of the BCD- and GHIJ-ring fragments through esterification, (ii) construction of the E-ring as a lactone form via reductive acetylation, (iii) stereoselective allylation to establish the C26 stereocenter, and (iv) ring-closing metathesis reaction to form the nine-membered F-ring." @default.
• W2077175348 created "2016-06-24" @default.
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• W2077175348 date "2007-06-01" @default.
• W2077175348 modified "2023-10-12" @default.
• W2077175348 title "Convergent synthesis of the BCDEFGHIJ-ring polyether core of gambieric acids, potent antifungal polycyclic ethers" @default.
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• W2077175348 doi "https://doi.org/10.1016/j.tet.2007.02.039" @default.
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