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- W2077185292 abstract "Abstract [1,3]-Sigmatropic rearrangement of 2-vinylsilirane (2-vinylsilacyclopropane) to silacyclopent-3-ene has been studied for the first time with quantum chemical methods. The PBE/TZ2P and B3LYP/6-31G(d) levels of theory have been used to explore the potential energy surface of the title reaction. The energies of the stationary points have also been evaluated with the G3(MP2)//B3LYP method. Several transition states corresponding to suprafacial and antarafacial pathways of the rearrangement have been found. The lowest energy pathway is a symmetry-allowed suprafacial sigmatropic shift with G3(MP2)//B3LYP activation energy of 97 kJ/mol." @default.
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- W2077185292 date "2010-02-01" @default.
- W2077185292 modified "2023-09-27" @default.
- W2077185292 title "Computational study of 2-vinylsilirane to silacyclopent-3-ene rearrangement" @default.
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- W2077185292 doi "https://doi.org/10.1016/j.theochem.2009.11.035" @default.
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