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- W2077203936 abstract "Abstract N-Tosyl-2-C-carbamoyl glycosides having the α- l -arabino- and β- d -xylo- configuration form under Mitsunobu conditions 2-C:3-N-carbonyl-2,3-dideoxy-3-N-tosylamino-α- l -lyxo- and β- d -arabinopyranosides, respectively, having the β-lactam ring fused to the pyranoid one; neither the formation of the γ-lactam ring nor that of the 3,4-epoxide were observed. The γ-lactam 2-C:4-N-carbonyl-2,4-dideoxy-4-N-tosylamino-β- d -xylopyranoside can be obtained after protection of the 3-hydroxy group in the starting glycoside of α- l -arabino-configuration. The structure and configuration of methyl 2-C:3-N-carbonyl-2,3-dideoxy-3-N-tosylamino-β- d -ribopyranoside and methyl 2-C:3-N-carbonyl-2,3-dideoxy-3-N-tosylamino-β- d -erythro-pyranosid-4-ulose were proved by X-ray crystallography." @default.
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- W2077203936 date "1998-02-01" @default.
- W2077203936 modified "2023-09-27" @default.
- W2077203936 title "Formation of β-lactams fused to the pyranoid ring via the Mitsunobu reaction" @default.
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- W2077203936 doi "https://doi.org/10.1016/s0008-6215(98)00017-2" @default.
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