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- W2077217377 abstract "The title complex, {[Mn(C(10)H(8)N(2))(2)(H(2)O)(2)](C(14)H(9)O(4)S(2))(2)}(n), contains an octa-hedrally coordinated Mn(II) cation and 2-(2-carboxy-phenyl-disulfan-yl)benzoate anions. The Mn(II) center is situated on a crystallographic center of inversion and is coordinated by four 4,4'-bipyridine (4,4'-bipy) ligands and two water mol-ecules. The 4,4'-bipy ligands act as bridging ligands, producing a fishing-net-like two-dimensional framework. In the crystal structure, this positively charged framework is charge balanced by 2-(2-carboxy-phenyl-disulfan-yl)benzoate anions that form a separate anionic two-dimensional framework via inter-molecular O-H⋯O hydrogen bonds and C-H⋯π stacking inter-actions. Additional inter-molecular O-H⋯O hydrogen bonds link the cationic and anionic frameworks to form the three-dimensional crystal structure." @default.
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- W2077217377 date "2009-04-22" @default.
- W2077217377 modified "2023-09-23" @default.
- W2077217377 title "Poly[[diaquabis(μ<sub>2</sub>-4,4′-bipyridine)manganese(II)] bis[2-(2-carboxyphenyldisulfanyl)benzoate]]" @default.
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- W2077217377 doi "https://doi.org/10.1107/s1600536809013646" @default.
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