FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077282142> ?p ?o ?g. }

• W2077282142 endingPage "2141" @default.
• W2077282142 startingPage "2134" @default.
• W2077282142 abstract "Treatment of the tetrafluorobenzyne complex Cp*Ir(η2-C6F4)(PMe3) (1) with MeCO2H affords the tetrafluorophenyl complex Cp*Ir(2,3,4,5,-C6F4H)(PMe3)(O2CMe) (2), which, on treatment with NaBH4, affords the hydride complex Cp*Ir(2,3,4,5,-C6F4H)(PMe3)H (3). Treatment of 3 with n-BuLi affords the trifluorobenzyne complex Cp*Ir(3,4,5-C6F3H)(PMe3) (4). Treatment of 4 with MeCO2H gives a mixture of two protonation products, Cp*Ir(2,3,4-C6F3H2)(PMe3)(O2CMe) (5) and Cp*Ir(3,4,5-C6F3H2)(PMe3)(O2CMe) (6) in an 8:1 ratio. Treatment of the 5/6 mixture with CF3CO2H affords 1,2,3-C6F3H3 and Cp*Ir(O2CCF3)2(PMe3) but at dramatically different rates, with 5 reacting significantly faster than 6. Treatment of 1a with Br2, I2, or MeI gives the oxidative addition products Cp*Ir(2-C6BrF4)Br(PMe3) (7), Cp*Ir(2-C6IF4)I(PMe3) (8), or Cp*Ir(2-C6MeF4)I(PMe3) (9), respectively. The variable-temperature proton NMR spectra of complexes 7 and 8 reveal an unusual restricted rotation about the Ir−PMe3 bonds on the NMR time scale (7, ΔG⧧ = 39 ± 2 kJ mol-1; 8, ΔG⧧ = 38 ± 2 kJ mol-1). Similarly, treatment of Cp*Rh(η2-C6F4)(PMe3) (1b) with I2 leads to formation of Cp*Rh(2-C6IF4)I(PMe3) (10), which also exhibits restricted rotation about the metal−phosphorus bond (ΔG⧧ = 44 ± 2 kJ mol-1). While the tetrafluorobenzyne complex (1a) is unreactive toward CO, the hydrocarbon analogue Cp*Ir(η2-C6H4)(PMe3) (1c) does react to give the CO monoinsertion product (11). Compound 1c also reacts with I2 to afford Cp*Ir(2-C6IH4)I(PMe3) (12), which also shows restricted rotation about the Ir−PMe3 bond (ΔG⧧ = 43 ± 2 kJ mol-1). X-ray crystal structures of complexes 3, 4, 5, 7, 8, 10, and 11 are reported." @default.
• W2077282142 created "2016-06-24" @default.
• W2077282142 creator A5007226824 @default.
• W2077282142 creator A5057803757 @default.
• W2077282142 creator A5065653694 @default.
• W2077282142 creator A5070630921 @default.
• W2077282142 creator A5076191791 @default.
• W2077282142 creator A5080942296 @default.
• W2077282142 date "2003-03-29" @default.
• W2077282142 modified "2023-10-03" @default.
• W2077282142 title "Reactions of Iridium and Rhodium Complexes Containing η²-Benzyne, η²-Tetrafluorobenzyne, and η²-Trifluorobenzyne Ligands. Differential Rates of Arene Elimination by Protonation of Isomeric Fluoroaryl Complexes and Restricted Rotation of PMe₃ Ligands in <i>o</i><i>rtho-</i>Iodo and <i>o</i><i>rtho-</i>Bromoaryl Complexes" @default.
• W2077282142 cites W1964150307 @default.
• W2077282142 cites W1985996040 @default.
• W2077282142 cites W1991980693 @default.
• W2077282142 cites W1993804221 @default.
• W2077282142 cites W1998329735 @default.
• W2077282142 cites W2036196346 @default.
• W2077282142 cites W2061357444 @default.
• W2077282142 cites W2101748147 @default.
• W2077282142 cites W2107158355 @default.
• W2077282142 cites W2154796632 @default.
• W2077282142 cites W273342346 @default.
• W2077282142 cites W2953055013 @default.
• W2077282142 doi "https://doi.org/10.1021/om030048w" @default.
• W2077282142 hasPublicationYear "2003" @default.
• W2077282142 type Work @default.
• W2077282142 sameAs 2077282142 @default.
• W2077282142 citedByCount "40" @default.
• W2077282142 countsByYear W20772821422012 @default.
• W2077282142 countsByYear W20772821422013 @default.
• W2077282142 countsByYear W20772821422014 @default.
• W2077282142 countsByYear W20772821422015 @default.
• W2077282142 countsByYear W20772821422016 @default.
• W2077282142 countsByYear W20772821422022 @default.
• W2077282142 crossrefType "journal-article" @default.
• W2077282142 hasAuthorship W2077282142A5007226824 @default.
• W2077282142 hasAuthorship W2077282142A5057803757 @default.
• W2077282142 hasAuthorship W2077282142A5065653694 @default.
• W2077282142 hasAuthorship W2077282142A5070630921 @default.
• W2077282142 hasAuthorship W2077282142A5076191791 @default.
• W2077282142 hasAuthorship W2077282142A5080942296 @default.
• W2077282142 hasConcept C115624301 @default.
• W2077282142 hasConcept C116569031 @default.
• W2077282142 hasConcept C145148216 @default.
• W2077282142 hasConcept C155647269 @default.
• W2077282142 hasConcept C161790260 @default.
• W2077282142 hasConcept C170493617 @default.
• W2077282142 hasConcept C178790620 @default.
• W2077282142 hasConcept C185592680 @default.
• W2077282142 hasConcept C2775968720 @default.
• W2077282142 hasConcept C2777961443 @default.
• W2077282142 hasConcept C30095370 @default.
• W2077282142 hasConcept C521398313 @default.
• W2077282142 hasConcept C528581852 @default.
• W2077282142 hasConcept C544153396 @default.
• W2077282142 hasConcept C55493867 @default.
• W2077282142 hasConcept C71240020 @default.
• W2077282142 hasConcept C8010536 @default.
• W2077282142 hasConcept C94882840 @default.
• W2077282142 hasConceptScore W2077282142C115624301 @default.
• W2077282142 hasConceptScore W2077282142C116569031 @default.
• W2077282142 hasConceptScore W2077282142C145148216 @default.
• W2077282142 hasConceptScore W2077282142C155647269 @default.
• W2077282142 hasConceptScore W2077282142C161790260 @default.
• W2077282142 hasConceptScore W2077282142C170493617 @default.
• W2077282142 hasConceptScore W2077282142C178790620 @default.
• W2077282142 hasConceptScore W2077282142C185592680 @default.
• W2077282142 hasConceptScore W2077282142C2775968720 @default.
• W2077282142 hasConceptScore W2077282142C2777961443 @default.
• W2077282142 hasConceptScore W2077282142C30095370 @default.
• W2077282142 hasConceptScore W2077282142C521398313 @default.
• W2077282142 hasConceptScore W2077282142C528581852 @default.
• W2077282142 hasConceptScore W2077282142C544153396 @default.
• W2077282142 hasConceptScore W2077282142C55493867 @default.
• W2077282142 hasConceptScore W2077282142C71240020 @default.
• W2077282142 hasConceptScore W2077282142C8010536 @default.
• W2077282142 hasConceptScore W2077282142C94882840 @default.
• W2077282142 hasIssue "10" @default.
• W2077282142 hasLocation W20772821421 @default.
• W2077282142 hasOpenAccess W2077282142 @default.
• W2077282142 hasPrimaryLocation W20772821421 @default.
• W2077282142 hasRelatedWork W1965190054 @default.
• W2077282142 hasRelatedWork W2006351894 @default.
• W2077282142 hasRelatedWork W2025325464 @default.
• W2077282142 hasRelatedWork W2026118354 @default.
• W2077282142 hasRelatedWork W2056695762 @default.
• W2077282142 hasRelatedWork W2079257864 @default.
• W2077282142 hasRelatedWork W2313504019 @default.
• W2077282142 hasRelatedWork W2515935008 @default.
• W2077282142 hasRelatedWork W4244248048 @default.
• W2077282142 hasRelatedWork W4283463443 @default.
• W2077282142 hasVolume "22" @default.
• W2077282142 isParatext "false" @default.
• W2077282142 isRetracted "false" @default.
• W2077282142 magId "2077282142" @default.
• W2077282142 workType "article" @default.