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- W2077305846 abstract "The reactivity of the phosphino-thiosemicarbazone ligand 2-(2-(diphenylphosphino)benzylidene)-N-ethylthiosemicarbazone (HLPEt) toward M(I) halides (M = Cu, Ag, Au) was studied. The complexes obtained, with formulae [Cu(HLPEt)2]Br (1), [Cu(HLPEt)2]I·2H2O (2), [Ag(HLPEt)(LPEt)]·3H2O (3), [Au2(HLPEt)2Cl]Cl·CH3OH (4) were satisfactorily characterized by elemental analysis, IR, ESI and 1H/31P NMR. Moreover, we have obtained the crystal structure of the ligand HLPEt and its sulfide oxidized form HLP(S)Et, which represents a new case of desulfurization process in thiosemicarbazone ligands. In addition, we present the crystal structure of the complexes 1 + H2O + 3MeOH and [Au2(HLPEt)4Cl]Cl·3CH3OH (5), together with their interesting crystal packing. The complex 5 is an interesting case of a pseudo-chloronium gold(I) complex. The ligand HLPEt and the complexes 3 and 4 display intense luminescence at room temperature." @default.
- W2077305846 created "2016-06-24" @default.
- W2077305846 creator A5014974858 @default.
- W2077305846 creator A5032926604 @default.
- W2077305846 date "2010-01-01" @default.
- W2077305846 modified "2023-09-27" @default.
- W2077305846 title "A thiosemicarbazone ligand functionalized by a phosphine group: Reactivity toward coinage metal ions" @default.
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- W2077305846 doi "https://doi.org/10.1039/b918962a" @default.
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