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• W2077306723 abstract "Broadband dielectric spectroscopy (10-1−107 Hz) is employed to study the molecular dynamics in a set of dendritic poly(ether amide)s involving three generations. In the amorphous systems a dynamic glass transition is found which scales well with calorimetric data. Additionally, one broadened or two frequency separated secondary relaxations are detected. They are assigned to local fluctuations of the ester, amide, and Boc-protected amine groups. This interpretation is confirmed by IR spectroscopy and calculations of the dipole moment of the fluctuating moieties." @default.
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• W2077306723 date "2000-04-21" @default.
• W2077306723 modified "2023-10-17" @default.
• W2077306723 title "Broadband Dielectric Spectroscopy on the Molecular Dynamics in Dendritic Model Systems" @default.
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• W2077306723 doi "https://doi.org/10.1021/ma9921854" @default.
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