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• W2077314935 abstract "Active dissolution and passivation of transition metals in alkali solutions is of technological importance in batteries. The performance of alkaline batteries is decided by the presence of halides as they influence passivation. Cyclic voltammetric studies were carried out on iron in different sodium hydroxide solutions in presence of halides. In alkali solutions iron formed hydroxo complexes and their polymers in the interfacial diffusion layer. With progress of time they formed a cation selective layer. The diffusion layer turned into bipolar ion selective layer consisted of halides, a selective inner sublayer to the metal side and cation selective outer layer to the solution side. At very high anodic potentials, dehydration and deprotonation led to the conversion of salt layer into an oxide." @default.
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• W2077314935 date "2008-02-01" @default.
• W2077314935 modified "2023-09-23" @default.
• W2077314935 title "The role of halide ions on the electrochemical behaviour of iron in alkali solutions" @default.
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• W2077314935 doi "https://doi.org/10.1016/j.apsusc.2007.09.019" @default.
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