FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077329807> ?p ?o ?g. }

• W2077329807 endingPage "847" @default.
• W2077329807 startingPage "847" @default.
• W2077329807 abstract "Several 0D, 1D, and 3D metal–organic hybrid frameworks of ZnII have been synthesized by using the asymmetric ligand 6-(1H-benzoimidazol-2-yl)pyridinecarboxylic acid (HL) with control of the temperature and solvent in a solvothermal synthesis technique. In DMF, the structure at room temperature confirms that the resulting compound Zn(L)2·2(H2O) (1) is the 0D mononuclear structure, above ∼80 °C, C–N bond cleavage of partial DMF molecules induces the formation of the 1D chain-like compound {[Zn(L)(HCOO)]·2(H2O)}n (2), but on warming up to 120 and 160 °C, due to the decomposition of a large number of DMF molecules, the same reaction, respectively, gives two 3D metal–organic coordination polymers with 3D channels reported previously {[Zn(HCOO)3]−·[H2N(CH3)2]+}n (3) and [Zn(HCOO)2]n (4), in which the 3D channels of 3 contain guest [H2N(CH3)2]+ motifs, while at high temperature the 3D channels of 4 are an open stable system without any guest molecules. Replacing DMF in the above reaction by ethanol or acetonitrile, only 0D compound 1 is obtained in the range from room temperature to 160 °C. However, the same reaction in DMSO provides a 1D wave-like compound {[Zn(L)(DMSO)]·(ClO4)·H2O}n (5), in which the solvent DMSO molecule coordinates to the central metal ZnII ion. Furthermore, in three new complexes 1, 2 and 5, through π⋯π stacking and hydrogen bonding interactions, 3D supramolecular networks are assembled. It is worth noting that the existence of the twelve-membered cyclic water–perchlorate dimers [(ClO4)⋯(H2O)]22− with chair-conformation in the solid state of 5 not only increases the stability of the supramolecular structure, but also results in a stronger fluorescence signal compared with ligand HL, 1 and 2." @default.
• W2077329807 created "2016-06-24" @default.
• W2077329807 creator A5006118160 @default.
• W2077329807 creator A5015563942 @default.
• W2077329807 creator A5020553497 @default.
• W2077329807 creator A5025929395 @default.
• W2077329807 creator A5037989560 @default.
• W2077329807 creator A5053432423 @default.
• W2077329807 creator A5074984127 @default.
• W2077329807 date "2009-01-01" @default.
• W2077329807 modified "2023-10-16" @default.
• W2077329807 title "Temperature- and solvent-controlled dimensionality in a zinc 6-(1H-benzoimidazol-2-yl)pyridinecarboxylate system" @default.
• W2077329807 cites W1820345752 @default.
• W2077329807 cites W1964858487 @default.
• W2077329807 cites W1968628941 @default.
• W2077329807 cites W1972646318 @default.
• W2077329807 cites W1974791136 @default.
• W2077329807 cites W1974910241 @default.
• W2077329807 cites W1977941554 @default.
• W2077329807 cites W1978659336 @default.
• W2077329807 cites W1979278752 @default.
• W2077329807 cites W1984555010 @default.
• W2077329807 cites W1988075596 @default.
• W2077329807 cites W1988770406 @default.
• W2077329807 cites W1990659739 @default.
• W2077329807 cites W1992174133 @default.
• W2077329807 cites W1999908724 @default.
• W2077329807 cites W1999937609 @default.
• W2077329807 cites W2000929824 @default.
• W2077329807 cites W2002525676 @default.
• W2077329807 cites W2008334921 @default.
• W2077329807 cites W2010050149 @default.
• W2077329807 cites W2010190061 @default.
• W2077329807 cites W2022167379 @default.
• W2077329807 cites W2027011204 @default.
• W2077329807 cites W2031603041 @default.
• W2077329807 cites W2035140938 @default.
• W2077329807 cites W2040229494 @default.
• W2077329807 cites W2048586545 @default.
• W2077329807 cites W2049570016 @default.
• W2077329807 cites W2056253472 @default.
• W2077329807 cites W2059904846 @default.
• W2077329807 cites W2062552574 @default.
• W2077329807 cites W2065553374 @default.
• W2077329807 cites W2070422220 @default.
• W2077329807 cites W2077246828 @default.
• W2077329807 cites W2077616487 @default.
• W2077329807 cites W2077834700 @default.
• W2077329807 cites W2088401316 @default.
• W2077329807 cites W2090873549 @default.
• W2077329807 cites W2092846178 @default.
• W2077329807 cites W2095389740 @default.
• W2077329807 cites W2101000826 @default.
• W2077329807 cites W2119952423 @default.
• W2077329807 cites W2121904540 @default.
• W2077329807 cites W2130964507 @default.
• W2077329807 cites W2132059560 @default.
• W2077329807 cites W2134826875 @default.
• W2077329807 cites W2152932169 @default.
• W2077329807 cites W2155113974 @default.
• W2077329807 cites W2158744361 @default.
• W2077329807 cites W2952670228 @default.
• W2077329807 doi "https://doi.org/10.1039/b819800d" @default.
• W2077329807 hasPublicationYear "2009" @default.
• W2077329807 type Work @default.
• W2077329807 sameAs 2077329807 @default.
• W2077329807 citedByCount "55" @default.
• W2077329807 countsByYear W20773298072012 @default.
• W2077329807 countsByYear W20773298072013 @default.
• W2077329807 countsByYear W20773298072014 @default.
• W2077329807 countsByYear W20773298072015 @default.
• W2077329807 countsByYear W20773298072016 @default.
• W2077329807 countsByYear W20773298072018 @default.
• W2077329807 countsByYear W20773298072019 @default.
• W2077329807 countsByYear W20773298072020 @default.
• W2077329807 countsByYear W20773298072022 @default.
• W2077329807 crossrefType "journal-article" @default.
• W2077329807 hasAuthorship W2077329807A5006118160 @default.
• W2077329807 hasAuthorship W2077329807A5015563942 @default.
• W2077329807 hasAuthorship W2077329807A5020553497 @default.
• W2077329807 hasAuthorship W2077329807A5025929395 @default.
• W2077329807 hasAuthorship W2077329807A5037989560 @default.
• W2077329807 hasAuthorship W2077329807A5053432423 @default.
• W2077329807 hasAuthorship W2077329807A5074984127 @default.
• W2077329807 hasConcept C112887158 @default.
• W2077329807 hasConcept C116569031 @default.
• W2077329807 hasConcept C170493617 @default.
• W2077329807 hasConcept C178790620 @default.
• W2077329807 hasConcept C185592680 @default.
• W2077329807 hasConcept C2777463227 @default.
• W2077329807 hasConcept C2780471494 @default.
• W2077329807 hasConcept C32909587 @default.
• W2077329807 hasConcept C33347731 @default.
• W2077329807 hasConcept C535196362 @default.
• W2077329807 hasConcept C55493867 @default.
• W2077329807 hasConcept C8010536 @default.
• W2077329807 hasConcept C93275456 @default.
• W2077329807 hasConceptScore W2077329807C112887158 @default.

• next