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• W2077331830 abstract "Abstract The hydrothermal reaction of pyrazinetetrazole, copper(II) acetate monohydrate, molybdenum(VI) oxide and 1,2-ethylenediphosphonic acid yields the bimetallic oxide [{Cu4(pyztet)4(Hpyztet)(H2O)2}{Mo12O36(PO4)}]·2H2O (1·2H2O). The framework structure is constructed from {Mo12O36(PO4)}3 − clusters sandwiched between and linking {Cu4(pyztet)5(Hpyztet)(H2O)2}n3n + networks. The Cu(II)-pyrazinetetrazolate substructure contains both ‘4 + 2’ axially distorted and square planar Cu(II) sites. The six-coordinate sites are of two types: the first exhibits {CuN6} coordination to four tetrazolate and two pyrazine nitrogen donors, while the second enjoys {CuN4O2} coordination defined by three tetrazolates and one pyrazine nitrogen donor, an aqua ligand and an oxo-group bridging to the Keggin cluster." @default.
• W2077331830 created "2016-06-24" @default.
• W2077331830 creator A5056165811 @default.
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• W2077331830 date "2013-06-01" @default.
• W2077331830 modified "2023-09-26" @default.
• W2077331830 title "Polyoxometalate clusters as building blocks for oxide materials: Synthesis and structure of a three-dimensional copper-pyrazinetetrazolate/Keggin assembly" @default.
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• W2077331830 doi "https://doi.org/10.1016/j.inoche.2013.03.001" @default.
• W2077331830 hasPublicationYear "2013" @default.
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