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- W2077337334 abstract "Composition dependences of the glass transition temperature (Tg), the molecular weight between entanglements (Me) and the thin film deformation behaviour have been studied in two series of methyl methacrylate-based random copolymers. When the comonomer is styrene, increases in both Me and brittle behaviour accompany the decrease of Tg. When the comonomer is N-substituted maleimide, the same conclusions hold with increasing Tg. For both series of materials, a correlation is proposed between the number of skeletal bonds in an entanglement strand, Ne, and the quantity (Tg—Tcs), where Tcs is the lower temperature at which shear deformation is observed in thin films in competition with crazing." @default.
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- W2077337334 date "1995-01-01" @default.
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- W2077337334 title "On the role of entanglements in the embrittlement of poly(methyl methacrylate) based random copolymers" @default.
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- W2077337334 doi "https://doi.org/10.1016/0032-3861(95)99008-i" @default.
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