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- W2077360084 abstract "Ni-MgO catalysts with varying Ni/Mg ratios were prepared by co-precipitation and tested in sorbitol hydrogenolysis. At 473 K and 4 MPa H2, the best catalyst with Ni/Mg ratio of 3:7 exhibited 67.8% conversion and 80.8% total selectivity of ethylene glycol, 1,2-propylene glycol and glycerol. These catalysts were characterized by XRD, CO2-TPD and H2 chemisorption, revealing that the activity depended strongly on the basicity and Ni surface area. The reaction conditions were optimized, which were relatively mild for this chemoselective conversion." @default.
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- W2077360084 date "2013-09-01" @default.
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- W2077360084 title "Hydrogenolysis of biomass-derived sorbitol to glycols and glycerol over Ni-MgO catalysts" @default.
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- W2077360084 doi "https://doi.org/10.1016/j.catcom.2013.05.012" @default.
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