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• W2077378138 abstract "A carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins was developed by using a chiral spiro iridium catalyst, providing a highly efficient approach to the compounds with a chiral benzylmethyl center. The carboxy-directed hydrogenation prohibited the isomerization of the terminal olefins, and realized the chemoselective hydrogenation of various dienes. The concise enantioselective syntheses of (S)-curcudiol and (S)-curcumene were achieved by using this catalytic asymmetric hydrogenation as a key step." @default.
• W2077378138 created "2016-06-24" @default.
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• W2077378138 date "2014-01-01" @default.
• W2077378138 modified "2023-10-11" @default.
• W2077378138 title "Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: highly enantioselective and chemoselective access to a chiral benzylmethyl center" @default.
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• W2077378138 doi "https://doi.org/10.1039/c4ob00018h" @default.
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