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- W2077391189 abstract "Abstract The dependence on the reactant collisional and internal energy of the total cross sections of hydride-ion (H − or D − ) and HD − transfer reactions in the system C 2 D 4 + + CH 3 CD 2 CH 3 was investigated using vibrationally state-selected reactant ions and guided-beam techniques. The cross sections of formation of C 3 D 6 H + (D − abstraction from position 2 of the target molecule) and C 3 H 5 D + (HD − abstraction from positions 1 and 2) decreased with both collision and reactant ion internal energy as it is usual for exoergic processes. Formation of C 3 H 5 D 2 + (H − abstraction from position 1) exhibited a much smaller cross section raising from a threshold near the energy zero, suggesting a slightly endoergic process, in agreement with thermochemical calculations. The internal energy appears to be about 4 x more effective than the translational energy in overcoming the endoergicity barrier of this process." @default.
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- W2077391189 date "1996-09-01" @default.
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- W2077391189 title "Reactions of H−, D− and HD− transfer between an ethylene cation and propane CH3CD2CH3: a study of kinetics using state-selected reactants" @default.
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- W2077391189 doi "https://doi.org/10.1016/0301-0104(96)00165-6" @default.
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