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• W2077394622 abstract "We applied two methods of blind spectral decomposition (MILCA and SNICA) to quantitative and qualitative analysis of UV absorption spectra of several non-trivial mixture types. Both methods use the concept of statistical independence and aim at the reconstruction of minimally dependent components from a linear mixture. We examined mixtures of major ecotoxicants (aromatic and polyaromatic hydrocarbons), amino acids and complex mixtures of vitamins in a veterinary drug. Both MICLA and SNICA were able to recover concentrations and individual spectra with minimal errors comparable with instrumental noise. In most cases their performance was similar to or better than that of other chemometric methods such as MCR-ALS, SIMPLISMA, RADICAL, JADE and FastICA. These results suggest that the ICA methods used in this study are suitable for real life applications. Data used in this paper along with simple matlab codes to reproduce paper figures can be found at http://www.klab.caltech.edu/~kraskov/MILCA/spectra" @default.
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• W2077394622 date "2010-10-01" @default.
• W2077394622 modified "2023-09-25" @default.
• W2077394622 title "Independent components in spectroscopic analysis of complex mixtures" @default.
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• W2077394622 doi "https://doi.org/10.1016/j.chemolab.2010.05.023" @default.
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