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- W2077397320 endingPage "10640" @default.
- W2077397320 startingPage "10634" @default.
- W2077397320 abstract "The techniques of pulse radiolysis and emission spectroscopy have been used to determine absolute total emission yields for the XeBr* exciplex. By application of known formation and quenching rate constants and mechanisms, individual fluorescence yields have been determined for the unquenched three-body ionic recombination reaction, Xe2+ + Br- + Xe → XeBr* + 2Xe, Go+ = 3.40 ± 0.18, and for the reaction of electronically excited xenon atoms with CF3Br, Xe* + CF3Br → XeBr* + CF3, Go* = 0.68 ± 0.10. These experimental yields are compared to the predictions of current theoretical models, which allow calculation of the efficiency for each ion-pair recombination event and excited state reaction to give the fluorescent XeBr* exciplex as 75% and 36%, respectively." @default.
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- W2077397320 date "1996-01-01" @default.
- W2077397320 modified "2023-10-17" @default.
- W2077397320 title "Absolute Fluorescence Yields from Electron Irradiated Gases: XeBr*" @default.
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- W2077397320 doi "https://doi.org/10.1021/jp960129o" @default.
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