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• W2077403977 abstract "The solubilities of benzaldehyde and p-methylbenzaldehyde in aqueous solutions of polyoxyethylene glycol ethers of varying polyoxyethylene chain length have been measured at 25°. Solubility increases with surfactant concentration and is greater for benzaldehyde than p-methylbenzaldehyde. The start of the solubility curve neither corresponds to the critical micelle concentration (CMC) of the surfactant alone nor to that of the ternary system. On a molar basis, solubility increases with an increase in hydrophilic chain length but decreases if solubility is expressed in terms of the amount solubilized per ethylene oxide unit. The solubility of benzaldehyde in a lauryl derivative is the same as in a cetyl derivative of the same polyoxyethylene chain length, whereas the solubility of methylbenzaldehyde is greater in the surfactant with the longer hydrocarbon chain. From the solubility data and an examination of the ultraviolet absorption spectra in aqueous surfactant solutions and other solvents, it is suggested that the solubilization of benzaldehyde occurs in the polyoxyethylene region of the micelle, while p-methylbenzaldehyde is distributed between this region and the hydrocarbon interior. The solubilities of benzaldehyde and p-methylbenzaldehyde in aqueous solutions of polyoxyethylene glycol ethers of varying polyoxyethylene chain length have been measured at 25°. Solubility increases with surfactant concentration and is greater for benzaldehyde than p-methylbenzaldehyde. The start of the solubility curve neither corresponds to the critical micelle concentration (CMC) of the surfactant alone nor to that of the ternary system. On a molar basis, solubility increases with an increase in hydrophilic chain length but decreases if solubility is expressed in terms of the amount solubilized per ethylene oxide unit. The solubility of benzaldehyde in a lauryl derivative is the same as in a cetyl derivative of the same polyoxyethylene chain length, whereas the solubility of methylbenzaldehyde is greater in the surfactant with the longer hydrocarbon chain. From the solubility data and an examination of the ultraviolet absorption spectra in aqueous surfactant solutions and other solvents, it is suggested that the solubilization of benzaldehyde occurs in the polyoxyethylene region of the micelle, while p-methylbenzaldehyde is distributed between this region and the hydrocarbon interior." @default.
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• W2077403977 date "1964-12-01" @default.
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• W2077403977 title "Oxidation of Aldehydes Solubilized in Nonionic Surfactants I" @default.
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• W2077403977 doi "https://doi.org/10.1002/jps.2600531207" @default.
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