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- W2077407781 abstract "The reaction of [RuTPP(CO)] (TPP = meso-tetraphenyl porphinate dianion) with several monidentate ligands L(L = t-butyl isocyanide, triphenylphosphine, dimethylphenylphosphine, triethylphosphine, trimethylphosphite) yields novel ruthenium(II) derivatives of formula [Ru(TPP)L2], characterized by their visible, i.r. 1H n.m.r. spectra. The electrochemical behaviour of these complexes in a CH3CN-benzene 50%(v/v) mixture with TBAP or TBATFB as supporting elecgtrolyte, has been sutdied by employing cyclic voltammetry and controlled potential electrolysis. Both the first anodic and the first cathodic process observed involves an electron transfer at the central metal yielding ruthenium(III) and ruthenium(I) derivatives. The potentials related to these processes are strongly dependent on the nature of the ligand L. The influence of the π-bonding abilities of the ligand on the stabilization of the different oxidation states is discussed." @default.
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- W2077407781 date "1979-01-01" @default.
- W2077407781 modified "2023-10-18" @default.
- W2077407781 title "Synthesis and electrochemical behaviour of novel ruthenium(II) tetraphenylporphinate derivatives" @default.
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- W2077407781 doi "https://doi.org/10.1016/s0020-1693(00)95538-5" @default.
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