Matches in SemOpenAlex for { <https://semopenalex.org/work/W2077413144> ?p ?o ?g. }
- W2077413144 endingPage "3699" @default.
- W2077413144 startingPage "3694" @default.
- W2077413144 abstract "Ester enolate Claisen rearrangement of highly substituted amino acid allylic esters 4 allows for the synthesis of sterically demanding amino acids 5 with β-quaternary carbon centers. Because of enolate fixation by chelation, the rearrangement occurs in a highly diastereoselective fashion. The methodology is suitable not only for glycine derivatives but also for allylic esters of various amino acids. In this case amino acids with two vicinal quaternary carbon centers are created. With unsymmetrically substituted allylic esters like 4k−n the rearrangement proceeds with a high degree of diastereoselectivity." @default.
- W2077413144 created "2016-06-24" @default.
- W2077413144 creator A5088253534 @default.
- W2077413144 date "1996-01-01" @default.
- W2077413144 modified "2023-10-16" @default.
- W2077413144 title "Application of the Ester Enolate Claisen Rearrangement in the Synthesis of Amino Acids Containing Quaternary Carbon Centers" @default.
- W2077413144 cites W1964487763 @default.
- W2077413144 cites W1970262466 @default.
- W2077413144 cites W1970484777 @default.
- W2077413144 cites W1972241961 @default.
- W2077413144 cites W1977198215 @default.
- W2077413144 cites W1983060808 @default.
- W2077413144 cites W1991989818 @default.
- W2077413144 cites W1993986154 @default.
- W2077413144 cites W1997292006 @default.
- W2077413144 cites W2001634717 @default.
- W2077413144 cites W2003148151 @default.
- W2077413144 cites W2004665455 @default.
- W2077413144 cites W2008326907 @default.
- W2077413144 cites W2012171927 @default.
- W2077413144 cites W2014555901 @default.
- W2077413144 cites W2022415019 @default.
- W2077413144 cites W2030421553 @default.
- W2077413144 cites W2033770700 @default.
- W2077413144 cites W2035350618 @default.
- W2077413144 cites W2039837957 @default.
- W2077413144 cites W2050166845 @default.
- W2077413144 cites W2051426016 @default.
- W2077413144 cites W2052743325 @default.
- W2077413144 cites W2053351141 @default.
- W2077413144 cites W2054909162 @default.
- W2077413144 cites W2058122525 @default.
- W2077413144 cites W2060291238 @default.
- W2077413144 cites W2064101811 @default.
- W2077413144 cites W2068575282 @default.
- W2077413144 cites W2068956225 @default.
- W2077413144 cites W2074535898 @default.
- W2077413144 cites W2076373059 @default.
- W2077413144 cites W2086770576 @default.
- W2077413144 cites W2089133342 @default.
- W2077413144 cites W2098262761 @default.
- W2077413144 cites W2102106364 @default.
- W2077413144 cites W2107376287 @default.
- W2077413144 cites W2118923747 @default.
- W2077413144 cites W2128621368 @default.
- W2077413144 cites W2135675075 @default.
- W2077413144 cites W2136324990 @default.
- W2077413144 cites W2142251268 @default.
- W2077413144 cites W2144808448 @default.
- W2077413144 cites W2156764225 @default.
- W2077413144 cites W2169210550 @default.
- W2077413144 cites W2483736575 @default.
- W2077413144 cites W2949308722 @default.
- W2077413144 cites W2950530745 @default.
- W2077413144 cites W2951128258 @default.
- W2077413144 cites W2952231870 @default.
- W2077413144 cites W2952799475 @default.
- W2077413144 cites W2953195611 @default.
- W2077413144 cites W3023376281 @default.
- W2077413144 cites W4252274551 @default.
- W2077413144 doi "https://doi.org/10.1021/jo960014g" @default.
- W2077413144 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11667217" @default.
- W2077413144 hasPublicationYear "1996" @default.
- W2077413144 type Work @default.
- W2077413144 sameAs 2077413144 @default.
- W2077413144 citedByCount "53" @default.
- W2077413144 countsByYear W20774131442012 @default.
- W2077413144 countsByYear W20774131442013 @default.
- W2077413144 countsByYear W20774131442014 @default.
- W2077413144 countsByYear W20774131442015 @default.
- W2077413144 countsByYear W20774131442016 @default.
- W2077413144 countsByYear W20774131442017 @default.
- W2077413144 countsByYear W20774131442018 @default.
- W2077413144 countsByYear W20774131442019 @default.
- W2077413144 countsByYear W20774131442021 @default.
- W2077413144 crossrefType "journal-article" @default.
- W2077413144 hasAuthorship W2077413144A5088253534 @default.
- W2077413144 hasConcept C104779481 @default.
- W2077413144 hasConcept C120095180 @default.
- W2077413144 hasConcept C121349320 @default.
- W2077413144 hasConcept C140205800 @default.
- W2077413144 hasConcept C159985019 @default.
- W2077413144 hasConcept C161790260 @default.
- W2077413144 hasConcept C178790620 @default.
- W2077413144 hasConcept C185592680 @default.
- W2077413144 hasConcept C192562407 @default.
- W2077413144 hasConcept C201194858 @default.
- W2077413144 hasConcept C2777756961 @default.
- W2077413144 hasConcept C2780567667 @default.
- W2077413144 hasConcept C30975014 @default.
- W2077413144 hasConcept C515207424 @default.
- W2077413144 hasConcept C55493867 @default.
- W2077413144 hasConcept C71240020 @default.
- W2077413144 hasConceptScore W2077413144C104779481 @default.
- W2077413144 hasConceptScore W2077413144C120095180 @default.
- W2077413144 hasConceptScore W2077413144C121349320 @default.
- W2077413144 hasConceptScore W2077413144C140205800 @default.
- W2077413144 hasConceptScore W2077413144C159985019 @default.