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- W2077437984 abstract "Abstract The behavior of electrical resistivity during hydrogen (deuterium) ordering is investigated for Pd–H(D) alloys of various hydrogen concentrations around 50 K. The disordered hydrogen (deuterium) atoms are introduced by quenching from 100 K into liquid helium immediately before isothermal annealings. The disordered atoms order by migration of the atoms during the heating-up of the specimens. On the isothermal curves of the resistivity in the high temperature range, the resistivity increases at first and then adopts a constant value dependent on the annealing temperature. On the other hand, the resistivity increases and then decreases during isothermal annealing in the low temperature range, nevertheless the ordering is progressing. The annealing time, at which the resistivity maximum appears, and the resistivity value of the maximum increase with decreasing annealing temperature. Furthermore, the decreasing resistivity after the maximum saturates to a value dependent on each annealing temperature. Therefore, it becomes clear that an equilibrium amount of ordering depends on the temperature and the resistivity increases in the early stage of hydrogen (deuterium) ordering and decreases in the later stage. The resistivity maximum in the isothermal annealing curve is caused by the nucleation and growth of ordered domains of hydrogen (deuterium) atoms." @default.
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- W2077437984 date "2004-11-01" @default.
- W2077437984 modified "2023-09-27" @default.
- W2077437984 title "Resistivity behavior in isothermal annealing of Pd–H(D) alloys around 50K" @default.
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- W2077437984 doi "https://doi.org/10.1016/j.jallcom.2004.03.110" @default.
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