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- W2077478947 abstract "cis -Hydroxyl groups of hexopyranosides reacted with 9,9-dichlorofluorene to give fluoren-9-ylidene acetals, hydrogenolysis of which with AlClH 2 gave derivatives with axial fluren-9-yl ether and equatorial hydroxyl groups. 1,6-Anhydro-2,3- O -fluoren-9-ylidene-β- d -mannopyranose ( 9 ) was an exception which gave a 2:3 mixture of 2- and 3-fluoren-9-yl ethers because of the marked distortion of the pyranose ring. The fluoren-9-yl ether groups could be removed easily by catalytic hydrogenation or by hydrogenolysis with the Lewis acid-type mixed hydride AlCl 2 H." @default.
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- W2077478947 date "1992-09-01" @default.
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- W2077478947 title "Preparation of dioxolane-type fluoren-9-ylidene acetals of carbohydrates and their hydrogenolysis with AlClH 2 to give axial fluoren-9-yl ethers" @default.
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- W2077478947 doi "https://doi.org/10.1016/0008-6215(92)84177-t" @default.
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