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- W2077484166 abstract "Abstract Nitrogen NMR shieldings of phenyl- N -methylnitrone are shown to be quite sensitive to solvent effects. The dominant contribution to the solvent induced range of nitrogen shieldings is produced by the hydrogen bond donor ability of the solvents. This indicates that hydrogen bonding to an oxygen atom contiguous with a nitrogen atom can exert effects on the nitrogen shielding which are comparable with those exerted by direct hydrogen bonding to the nitrogen lone pair electrons in imine systems. Minor shielding changes due to solvent polarity polarizability are quite well reproduced by nitrogen shielding calculations incorporating the solvation model." @default.
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- W2077484166 date "1994-05-01" @default.
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- W2077484166 title "Solvent induced nitrogen NMR shielding variation of α-phenyl-N-methylnitrone" @default.
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- W2077484166 doi "https://doi.org/10.1016/0022-2860(93)07941-o" @default.
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