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- W2077497407 abstract "Three kinetic methods based on flow injection, flow, and stopped-flow injection were applied for the determination of Cd(II) using a flow-through bulk optode membrane that incorporates 1-(2-pyridylazo)-2-naphtol (PAN) in a plasticized poly(vinyl) chloride membrane entrapped in a cellulose support. The calibration graphs plotting the reflectance at 560 nm versus [Cd(II)](1/2) for the first two methods and versus [Cd(II)] for the third were linear up to 56.2 mg l(-1). The detection limits of the methods were 0.01, 0.06 and 0.8 mg l(-1), respectively. The FI method was selected for application purposes. The variation coefficient of the sensor response for 11.2 mg l(-1) of Cd(II) was +/-0.31 and +/-0.65% between different membranes. The sensor can be readily regenerated with a carrier (acetic-acetate) buffer of pH 4. The FI method was applied to the determination of cadmium in an alloy and in water." @default.
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- W2077497407 date "2002-03-04" @default.
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- W2077497407 title "Kinetic methods for the determination of cadmium(II) based on a flow-through bulk optode" @default.
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- W2077497407 doi "https://doi.org/10.1016/s0039-9140(01)00571-9" @default.
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