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- W2077498123 abstract "The electrokinetic and surface charge behavior of stannic oxide (SnO2) in KNO3 electrolyte solutions is reported as a function of pH and ionic strength. Potentiometric titrations of the surface groups showed that the point of zero charge occurred at pH 4.3 ± 0.1. The isoelectric point obtained from microelectrophoresis was at pH 4.5 ± 0.15. Stannic oxide behaved similarly to other insoluble metal oxides with respect to the effect of pH on its surface charge and zeta potential. Intrinsic equilibrium constants, which describe the ionization of surface hydroxyl groups and the ion-binding of electrolyte, were calculated using various estimates of the total hydroxyl site density and three different methods of calculation. The preferred values are NS = 11.2 OH groups per nm2, pKa1int = 0.7, pKa2int = 7.9, and p*KK+int = 6.3." @default.
- W2077498123 created "2016-06-24" @default.
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- W2077498123 date "1984-07-01" @default.
- W2077498123 modified "2023-10-05" @default.
- W2077498123 title "Surface titrations and electrokinetic measurements on stannic oxide suspensions" @default.
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- W2077498123 doi "https://doi.org/10.1016/0021-9797(84)90435-1" @default.
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