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- W2077510134 abstract "Abstract A wire-mesh reactor capable of multi-step heating/holding and minimising secondary reactions of volatiles was used to investigate the effects of thermal pretreatment in inert gas on the subsequent rapid pyrolysis behaviour of Loy Yang brown coal. Our results indicate that the presence of small amounts ( 250 °C leads to reduced tar and increased char yields. However, the characterisation of tars using UV-fluorescence spectroscopy indicates that significant decreases in the release of larger aromatic ring systems are only observed after preheating at >380 °C for 30 min. The presence of ion-exchangeable cations (e.g. Ca2+) in the brown coal tends to stabilise the carboxylate groups and only preheating at >350 °C would result in changes in pyrolysis yields during the subsequent pyrolysis at 1000 K s−1. These results may be explained by considering the formation of cross-links involving peripheral groups at low preheating temperatures and the formation of cross-links involving aromatic ring systems at elevated temperatures." @default.
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- W2077510134 date "2005-04-25" @default.
- W2077510134 modified "2023-10-03" @default.
- W2077510134 title "Effects of thermal pretreatment in helium on the pyrolysis behaviour of Loy Yang brown coal" @default.
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- W2077510134 doi "https://doi.org/10.1016/j.fuel.2005.02.025" @default.
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