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- W2077514998 abstract "A reversal in solvatochromic behaviour was observed in second and third generation glycerol based dansylated polyether dendrons in water on addition of a second solvent like methanol or acetonitrile. Below a certain percentage of the nonaqueous solvent there is a negative-solvatochromism observed and above that there is a switch to positive-solvatochromism. The negative-solvatochromism is attributed to the progressive disaggregation of the dendron aggregates by the nonaqueous solvent component. Once the disaggregation process is complete, positive-solvatochromism is exhibited by the dendron monomers. Higher the hydrophobicity of the dendron more is the amount of the second solvent required for disaggregation." @default.
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- W2077514998 date "2014-07-01" @default.
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- W2077514998 title "Disaggregation induced solvatochromic switch: A study of dansylated polyglycerol dendrons in binary solvent mixture" @default.
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- W2077514998 doi "https://doi.org/10.1016/j.saa.2014.02.150" @default.
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