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- W2077543302 abstract "The adsorption of bromine onto the basal (0001) surface of highly oriented pyrolytic graphite is studied as a function of pressure at 25°C by an ellipsometric technique. Below the intercalation threshold, the extend of adsorption is given directly by variations in Δ, in tan ψ exp(iΔ) = rp/rs, while ψ remains constant. At the threshold (20 torr Br2) ψ falls steeply because intercalation here causes a discontinuous change in the substrate optical constants n and k. Reasons are given for supposing the adsorbed bromine to be predominantly ionic (Br−2, Σu) at low coverages, but 13 ionic in the completed monolayer." @default.
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- W2077543302 date "1978-01-01" @default.
- W2077543302 modified "2023-09-27" @default.
- W2077543302 title "Ellipsometric investigation of the intercalation threshold in the graphite and bromine system" @default.
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- W2077543302 doi "https://doi.org/10.1016/0009-2614(78)85416-5" @default.
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