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• W2077576155 abstract "We have found a method for a diameter-selective removal of metallic single-walled carbon nanotubes (m-SWCNTs) from semiconducting (s-) ones by stirring or sonicating SWCNT powder in tetramethylene sulfone (TMS)/chloroform solution with nitronium hexafluoroantimonate (NO2SbF6: NHFA) and nitronium tetrafluoroborate (NO2BF4: NTFB). Positively charged nitronium ions (NO2+) were intercalated into nanotube bundles, where the intercalation was promoted also by the counterions. Nitronium ions selectively attacked the sidewall of the m-SWCNTs due to the abundant presence of electron density at the Fermi level, thus yielding stronger binding energy as compared to the counterpart s-SWCNTs. The s-SWCNTs were left on the filter after filtration, whereas the m-SWCNTs were disintegrated and drained away as amorphous carbons. The effectiveness of removing m-SWCNTs was confirmed by the resonant Raman spectra and absorption spectra." @default.
• W2077576155 created "2016-06-24" @default.
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• W2077576155 date "2005-03-17" @default.
• W2077576155 modified "2023-10-16" @default.
• W2077576155 title "A Diameter-Selective Attack of Metallic Carbon Nanotubes by Nitronium Ions" @default.
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• W2077576155 doi "https://doi.org/10.1021/ja0428199" @default.
• W2077576155 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15810855" @default.
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