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- W2077586019 abstract "A series of manganeseII/manganeseIII complexes have been synthesised utilising an exogenous anionic ligand OAc, SCN with tridentate bis (2-benzimidazolyl methyl) ether and tetradentate 1,2-bis(2-benzi-midazolyloxamethyl) benzene ligands. The visible spectra of the MnIII compounds suggests pseudo C4v symmetry, and the EPR data on the manganeseII complexes indicates a similar geometry. Cyclic-voltammetric studies reveal that the E12 for the manganeseII/manganeseIIIcouple shifts to a positive value with acetate as an anionic ligand, implying that this anion stabilises the manganeseII oxidation state while the E12, data for SCN reveals that the anion stabilises the manganeseIII state. The reoxidation step of the superoxide formed in the cyclic-voltammetric experiments becomes irreversible in the presence of manganese complexes ; suggesting that these complexes act as good quenchers for superoxide anion" @default.
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- W2077586019 date "1997-01-01" @default.
- W2077586019 modified "2023-09-22" @default.
- W2077586019 title "Manganese complexes of bis-benzimidazolyl ligand as novel quenchers of superoxide radical anion" @default.
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- W2077586019 doi "https://doi.org/10.1016/s0277-5387(97)00126-5" @default.
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