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- W2077592333 abstract "The synthesis and photochemical behavior of three types of polysiloxanes containing phenyldisilanyl units as chromophore have been reported. Irradiation of thin liquid films of the polymer (2) prepared from copolymerization of octamethylcyclotetrasiloxane and 1,3,5-triphenyl-1,3,5-tris(trimethylsilyl)cyclostrisiloxane (1) with a 500-W Xe-Hg lamp afforded transparent solid films which are insoluble in common organic solvents. Similar irradiation of thin liquid films of polysiloxane (8) containing both phenyldisilanyl units and vinyl groups resulted in formation of crosslinked solid films. When thick films of the polymers 2 and 8 were irradiated with a Xe-Hg lamp, crosslinking occurred only on the surface of the films, but inside remained as liquid. Irradiation of the films prepared from the polysiloxane involving the phenyldisilanyl units and butenyl groups, however, gave crosslinked solid films, whatever thickness of the films. The mechanism of photochemically induced crosslinking of the copolymers is discussed on the basis of the results obtained from the photolysis of 1,1-bis(trimethylsiloxy)-1-phenyl(trimethyl)disilane as a model compound." @default.
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- W2077592333 date "1986-07-01" @default.
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- W2077592333 title "Photolysis of polymeric organosilicon systems. III. Synthesis and photochemical behavior of polysiloxanes containing phenyldisilanyl units" @default.
- W2077592333 doi "https://doi.org/10.1002/pola.1986.080240713" @default.
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