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• W2077592777 abstract "Far-i.r. spectra in the region 20–600 cm−1 are reported for solid l-alanine as a function of temperature between 6 and 300 K. Understanding of the temperature-sensitive as well as the temperature-insensitive bands is aided by the normal coordinate analysis of l-alanine. Bands containing contributions from hydrogen bonds, skeletal deformation and NH3+ torsion are found to be highly sensitive to temperature changes. Although the hydrogen bonds are stronger at lower temperatures, no evidence of amide formation is detected even at 6 K. Thus the zwitterion form seems to be more stable than the amide form in the temperature range studied here." @default.
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• W2077592777 date "1983-01-01" @default.
• W2077592777 modified "2023-10-10" @default.
• W2077592777 title "The temperature-dependence of the far-infrared spectra of l-alanine" @default.
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• W2077592777 doi "https://doi.org/10.1016/0584-8539(83)80010-5" @default.
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