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- W2077599350 abstract "A series of framework substituted Co-TUD-1 catalysts, prepared by direct hydrothermal synthesis, were characterized using X-ray diffraction, nitrogen physisorption, transmission electron microscopy and UV–vis and Raman spectroscopies. These catalysts showed high conversion and selectivity towards trans-stilbene oxide in liquid phase trans-stilbene epoxidation with molecular oxygen as oxidant in the absence of a sacrificial reductant. The conversion and selectivity did not remarkably differentiate for fresh and recycled catalyst after four reaction runs. The unique pore structure of Co-TUD-1 catalyst is suggested to be beneficial for the epoxidation of bulky alkene molecules comparing with other well-established catalysts, e.g., Co-MCM-41 and Co2+-NaX. Microwave irradiation can significantly shorten the reaction time, whereas high conversion and epoxide selectivity remained." @default.
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- W2077599350 date "2009-06-01" @default.
- W2077599350 modified "2023-10-18" @default.
- W2077599350 title "Liquid phase trans-stilbene epoxidation over catalytically active cobalt substituted TUD-1 mesoporous materials (Co-TUD-1) using molecular oxygen" @default.
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- W2077599350 doi "https://doi.org/10.1016/j.apcata.2009.04.003" @default.
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