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- W2077600229 abstract "Treatment of diphenylvinylsilane with cyclic secondary amines(e.g. morpholine) in the presence of the corresponding lithium amides leads tosubstitution of the SiH hydrogen atom by an amino group and to addition of the amine to the vinyl group. A similar reaction observed in the case of2-thienylphenylvinylsilane is accompanied by cleavage of the SiC bond and substitution of the 2-thienyl group by an amino group. Die Umsetzung von Diphenyl-vinylsilan mit zyklischen sekundären Aminen (z.B. Morpholin) in Gegenwart der entsprechendenLithium-amide führt zu einer Substitution des an Silicium gebundenen H-Atomsdurch eine Aminogruppe und ze einer Addition des Amins an die Vinylgruppe.2-Thienylphenyl-vinylsilan reagiert jedoch zusätzlich unter Spaltung der SiC-Bindung und Aminosubstitution der 2-Thienylgruppe." @default.
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- W2077600229 date "1979-06-01" @default.
- W2077600229 modified "2023-09-26" @default.
- W2077600229 title "SiC-spaltung in 2-thienylsilanen durch sekundäre amine" @default.
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- W2077600229 doi "https://doi.org/10.1016/s0022-328x(00)81853-7" @default.
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