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- W2077607832 abstract "The kinetics of the degradation of acephate by water-soluble colloidal MnO2 in acidic medium (HClO4) has been studied spectrophotometrically in the absence and presence of surfactants. The experiments have been performed under the pseudo-first-order reaction conditions with respect to MnO2. The degradation has been observed to be fractional order with respect to acephate and HClO4 while first order with respect to MnO2 in the absence and presence of surfactants. It has been observed that cationic surfactant, cetyl trimethyl ammonium bromide, causes flocculation with oppositely charged colloidal MnO2 whereas anionic surfactant, sodium dodecyl sulfate, has no considerable effect on the reaction kinetics. However, non-ionic surfactant, Triton X-100 (TX-100) accelerates the reaction rate. The catalytic effect of TX-100 has been discussed in the light of the available mathematical model. The kinetic data have been used to calculate the different activation parameters for the oxidative degradation of acephate by colloidal MnO2." @default.
- W2077607832 created "2016-06-24" @default.
- W2077607832 creator A5008509312 @default.
- W2077607832 creator A5061261899 @default.
- W2077607832 date "2014-07-11" @default.
- W2077607832 modified "2023-09-25" @default.
- W2077607832 title "Degradation of acephate by colloidal manganese dioxide in the absence and presence of surfactants" @default.
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- W2077607832 doi "https://doi.org/10.1080/19443994.2014.937752" @default.
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