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- W2077646952 abstract "The polymerization of acrylonitrile initiated by titanium tetradimethylamide is described and discussed in some detail. A mechanism, which adequately accounts for the behaviour observed, is suggested; the kinetic consequences of the scheme are related to the experimental data. Some information about comparable reactivities of other transition metal compounds and other monomers is recorded. La polymérisation de l'acrylonitrile amorcée par du tetradiméthylamidure de titane est décrite et discutée en détail. On suggère un mécanisme qui rend compte correctement du comportement observé. Les conséquences cinétiques du schéma sont comparées aux données expérimentales. On donne quelques informations sur des réactivités comparables d'autres composés de métaux de transition et d'autres monomères. Si descrive e discute in alcuni particolari la polimerizzazione di acrilonitrile iniziata mediante tetradimetilamide di titanio. Si avanza la teoria di un meccanismo che spiega adeguatamente il comportamento osservato; i risultati cinetici sono messi in relazione con i dati sperimentali. Si riportano alcune informazioni circa le reattività comparabili di altri composti metallici di transizione e di altri monomeri. Die Polymerisation von Acrylnitril mit Titan-tetradimethyltamid als Initiator wird beschrieben und diskutiert. Es wird ein Mechanismus vorgeschlagen, der das beobachtete Verhalten in geeigneter Weise erklärt; die Folgerungen aus dem kinetischen Schema werden mit den experimentellen Daten verglichen. Einige Informationen über vergleichbare Reaktivitäten von anderen Übergangsmetallverbindungen und anderen Monomeren werden gegeben." @default.
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- W2077646952 date "1971-04-01" @default.
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- W2077646952 title "The initiation of polymerization by organometallic compounds—II. The polymerization of acrylonitrile with titanium tetradimethylamide and related reactions" @default.
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- W2077646952 doi "https://doi.org/10.1016/0014-3057(71)90001-2" @default.
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