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- W2077665689 abstract "Silica nanowires were synthesized by employing inherent directionality of chemical vapor reaction between bis(ethylmethylamino)silane (H2Si[N(C2H5)(CH3)]2) precursor and water without a metal catalyst at room temperature. The difference in the oxidation reactivity between Si−H and Si−N bonds with water leads to the formation of silica nanowires. The mean diameter and length of the silica nanowires grown for 10 min were 60−80 nm and 1.9 μm, respectively. Transmission electron microscopy revealed that the obtained nanowires had the concave tip, differing from other silica nanowires produced by a conventional vapor−liquid−solid method, and were amorphous. Energy dispersive X-ray spectroscopy, Fourier transform infrared, and X-ray photoelectron spectroscopy results also proved that the nanowires have a close composition to stoichiometric SiO2. Silica nanowires were successfully synthesized on a poly(ethylene terephthalate) film. The nanowires can emit strong blue light and ultraviolet light under excitation at 266 nm." @default.
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- W2077665689 date "2011-02-09" @default.
- W2077665689 modified "2023-10-17" @default.
- W2077665689 title "A Novel Route to the Synthesis of Silica Nanowires without a Metal Catalyst at Room Temperature by Chemical Vapor Deposition" @default.
- W2077665689 doi "https://doi.org/10.1021/nl103882t" @default.
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