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- W2077678429 abstract "Abstract Silicic acid provokes the expansion of both pure dihexadecyllecithin films and mixed cholesterol—dihexadecyllecithin films containing more than 60% of phospholipid. On silica-free substrates the plot of the mean molecular area against the composition of the mixed system showed a large negative deviation from ideal behaviour, particularly at low surface pressure, for which the graph shows inflections when the mole fraction of lecithin is 0.5 or 0.8. On silicic acid substrates the condensation caused by cholesterol is more noticeable, and there is no sharp inflection in the mean molecular area plot. These results are interpreted as suggesting that silicic acid causes a change in the orientation of the phosphatidylcholine group of the lecithin, as a result of which the electrostatic repulsion between neighbouring molecules becomes greater, leading to more expanded films." @default.
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- W2077678429 date "1985-06-01" @default.
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- W2077678429 title "The interaction of polysilicic acid with mixed films of cholesterol and dihexadecyllecithin" @default.
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- W2077678429 doi "https://doi.org/10.1016/0166-6622(85)80179-7" @default.
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