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- W2077686195 abstract "A neodymium-containing catalytic system has been used to synthesize homopolymers of 2-alkyl butadienes-1,3 (A), where the alkyl is ethyl or isopropyl, and the copolymers of A with butadiene-1,3 (B) mostly containing (>95%) cis-1,4-units (1H and 13C NMR). The sole disturbance of the regularity of the construction of the macromolecular chain is the presence of the 3,4-units the fraction of which in the alkyl butadiene fragment of the copolymers falls with rise in the B content. The relative activity of compound A in copolymerization (rA) is higher than for compound B (rB). The distribution of the monomer units differs somewhat from the Bernoulli in the raised content of the diad AA and BB sequences." @default.
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- W2077686195 date "1987-01-01" @default.
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- W2077686195 title "Cis-1,4-copolymerization of butadiene and 2-alkyl butadienes" @default.
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- W2077686195 doi "https://doi.org/10.1016/0032-3950(87)90415-1" @default.
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